Film | Villain | Portrayed By |
| Dr. No | Dr. Julius No | Joseph Wiseman |
| From Russia with Love | Rosa Klebb | Lotte Lenya |
| Ernst Stavro Blofeld | Anthony Dawson |
| Goldfinger | Auric Goldfinger | Gert Frobe |
| Thunderball | Emilio Largo | Adolfo Celi |
| Ernst Stavro Blofeld | Anthony Dawson |
| You Only Live Twice | Ernst Stavro Blofeld | Donald Pleasence |
| On Her Majesty's Secret Service | Ernst Stavro Blofeld | Telly Savalas |
| Diamonds Are Forever | Ernst Stavro Blofeld | Charles Gray |
| For Your Eyes Only | Ernst Stavro Blofeld | John Hollis (uncredited) |
| Ernst Stavro Blofeld | Robert Rietty (voice/uncredited) |
| Live and Let Die | Dr. Kananga/Mr. Big | Yaphet Kotto |
| The Man with the Golden Gun | Francisco Scaramanga | Christopher Lee |
| The Spy Who Loved | MeKarl Stromberg | Curd Jürgens |
| Moonraker | Sir Hugo Drax | Michael Lonsdale |
| For Your Eyes Only | Aris Kristatos | Julian Glover |
| Octopussy | Kamal Khan | Louis Jourdan |
| General Orlov | Steven Berkoff |
| A View to a Kill | Max Zorin | Christopher Walken |
| The Living Daylights | Brad Whitaker | Joe Don Baker |
| General Koskov | Jeroen Krabbé |
| Licence to Kill | Franz Sanchez | Robert Davi |
| GoldenEye | Alec Trevelyan (006) | Sean Bean |
| Tomorrow Never Dies | Elliot Carver | Jonathan Pryce |
| The World Is Not Enough | Elektra King | Sophie Marceau |
| Viktor 'Renard' Zokas | Robert Carlyle |
| Die Another Day | Gustav Graves (Colonel Moon) | Toby Stephens (Will Yun Lee) |
| Casino Royale | Le Chiffre | Mads Mikkelsen |
| Mr. White | Jesper Christensen |
| Quantum of Solace | Dominic Greene | Mathieu Amalric |
Villians in non-EON Bond films |
| Casino Royale — 1954 TV episode | Le Chiffre | Peter Lorre |
| Casino Royale — 1967 film | Le Chiffre | Orson Welles |
| Dr. Noah/Jimmy Bond | Woody Allen |
| Never Say Never Again | Maximillian Largo | Klaus Maria Brandauer |
| Ernst Stavro Blofeld | Max von Sydow |
A great source site. | James Bond Wiki |